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Beilstein J. Org. Chem. 2020, 16, 492–501, doi:10.3762/bjoc.16.44
Graphical Abstract
Scheme 1: Comparison of different ring-opening reactions of 2-oxazolines and thiazolidinones synthesis.
Scheme 2: KOt-Bu-promoted selective ring-opening N-alkylation of 2-methyl-2-oxazoline with benzyl bromides. C...
Scheme 3: KOt-Bu-promoted selective ring-opening N-alkylation of 2-methyl-2-oxazoline with benzyl chlorides. ...
Scheme 4: KOt-Bu-promoted selective ring-opening N-alkylation of 2,4,4-trimethyl-4,5-dihydrooxazole (2b) with...
Scheme 5: KOt-Bu/I2-promoted selective N-alkylation to synthesis of thiazolidone derivatives. Conditions: KOt...
Scheme 6: Transformation of 2-aminoethyl acetate derivative to 2-(dibenzylamino)ethanol.
Scheme 7: Control experiments and 18O-labeling experiment.
Scheme 8: Control experiments with radical scavengers.
Scheme 9: Proposed mechanism.